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The Argentina international was on target in Manuel Pellegrini's team's 3-0 away win against Viktoria Plzen in Group D.
"A very motivating start for the Champion's - enjoying the victory but with our minds on Sunday's derby. C'mon City!" Aguero wrote on his Twitter page.
Edin Dzeko and Yaya Toure also scored for City against Plzen.
No Data Analysis infoRestore Data
| Team | P | W | D | L | PTS | |
| 1 | Liverpool | 4 | 4 | 0 | 0 | 12 |
| 2 | Sporting Lisbon | 4 | 3 | 1 | 0 | 10 |
| 3 | Brest | 4 | 3 | 1 | 0 | 10 |
| 4 | Inter Milan | 4 | 3 | 1 | 0 | 10 |
| 5 | Monaco | 4 | 3 | 1 | 0 | 10 |
| 6 | Barcelona | 4 | 3 | 0 | 1 | 9 |
| 7 | Dortmund | 4 | 3 | 0 | 1 | 9 |
| 8 | Aston Villa | 4 | 3 | 0 | 1 | 9 |
| 9 | Atalanta | 4 | 2 | 2 | 0 | 8 |
| 10 | Juventus | 4 | 2 | 1 | 1 | 7 |
| 11 | Lille | 4 | 2 | 1 | 1 | 7 |
| 12 | Man City | 4 | 2 | 1 | 1 | 7 |
| 13 | Arsenal | 4 | 2 | 1 | 1 | 7 |
| 14 | B. Leverkusen | 4 | 2 | 1 | 1 | 7 |
| 15 | Celtic | 4 | 2 | 1 | 1 | 7 |
| 16 | Dinamo Zagreb | 4 | 2 | 1 | 1 | 7 |
| 17 | AC Milan | 4 | 2 | 0 | 2 | 6 |
| 18 | Bayern | 4 | 2 | 0 | 2 | 6 |
| 19 | Benfica | 4 | 2 | 0 | 2 | 6 |
| 20 | Feyenoord | 4 | 2 | 0 | 2 | 6 |
| 21 | Real Madrid | 4 | 2 | 0 | 2 | 6 |
| 22 | Brugge | 4 | 2 | 0 | 2 | 6 |
| 23 | Atletico | 4 | 2 | 0 | 2 | 6 |
| 24 | PSV | 4 | 1 | 2 | 1 | 5 |
| 25 | Sparta Prague | 4 | 1 | 1 | 2 | 4 |
| 26 | Stuttgart | 4 | 1 | 1 | 2 | 4 |
| 27 | PSG | 4 | 1 | 1 | 2 | 4 |
| 28 | Shakhtar | 4 | 1 | 1 | 2 | 4 |
| 29 | Girona | 4 | 1 | 0 | 3 | 3 |
| 30 | Salzburg | 4 | 1 | 0 | 3 | 3 |
| 31 | Bologna | 4 | 0 | 1 | 3 | 1 |
| 32 | RB Leipzig | 4 | 0 | 0 | 4 | 0 |
| 33 | Sturm Graz | 4 | 0 | 0 | 4 | 0 |
| 34 | Young Boys | 4 | 0 | 0 | 4 | 0 |
| 35 | Red Star | 4 | 0 | 0 | 4 | 0 |
| 36 | Slovan Bratislava | 4 | 0 | 0 | 4 | 0 |
