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The Argentina international was on target in Manuel Pellegrini's team's 3-0 away win against Viktoria Plzen in Group D.
"A very motivating start for the Champion's - enjoying the victory but with our minds on Sunday's derby. C'mon City!" Aguero wrote on his Twitter page.
Edin Dzeko and Yaya Toure also scored for City against Plzen.
No Data Analysis infoRestore Data
| Team | P | W | D | L | PTS | |
| 1 | Dortmund | 2 | 2 | 0 | 0 | 6 |
| 2 | B. Leverkusen | 2 | 2 | 0 | 0 | 6 |
| 3 | Benfica | 2 | 2 | 0 | 0 | 6 |
| 4 | Brest | 2 | 2 | 0 | 0 | 6 |
| 5 | Aston Villa | 2 | 2 | 0 | 0 | 6 |
| 6 | Liverpool | 2 | 2 | 0 | 0 | 6 |
| 7 | Juventus | 2 | 2 | 0 | 0 | 6 |
| 8 | Inter Milan | 2 | 1 | 1 | 0 | 4 |
| 9 | Man City | 2 | 1 | 1 | 0 | 4 |
| 10 | Atalanta | 2 | 1 | 1 | 0 | 4 |
| 11 | Arsenal | 2 | 1 | 1 | 0 | 4 |
| 12 | Sparta Prague | 2 | 1 | 1 | 0 | 4 |
| 13 | Sporting Lisbon | 2 | 1 | 1 | 0 | 4 |
| 14 | Monaco | 2 | 1 | 1 | 0 | 4 |
| 15 | Lille | 2 | 1 | 0 | 1 | 3 |
| 16 | Bayern | 2 | 1 | 0 | 1 | 3 |
| 17 | Barcelona | 2 | 1 | 0 | 1 | 3 |
| 18 | Real Madrid | 2 | 1 | 0 | 1 | 3 |
| 19 | PSG | 2 | 1 | 0 | 1 | 3 |
| 20 | Celtic | 2 | 1 | 0 | 1 | 3 |
| 21 | Brugge | 2 | 1 | 0 | 1 | 3 |
| 22 | Atletico | 2 | 1 | 0 | 1 | 3 |
| 23 | Feyenoord | 2 | 1 | 0 | 1 | 3 |
| 24 | Bologna | 2 | 0 | 1 | 1 | 1 |
| 25 | Shakhtar | 2 | 0 | 1 | 1 | 1 |
| 26 | PSV | 2 | 0 | 1 | 1 | 1 |
| 27 | Stuttgart | 2 | 0 | 1 | 1 | 1 |
| 28 | Dinamo Zagreb | 2 | 0 | 1 | 1 | 1 |
| 29 | Girona | 2 | 0 | 0 | 2 | 0 |
| 30 | RB Leipzig | 2 | 0 | 0 | 2 | 0 |
| 31 | Sturm Graz | 2 | 0 | 0 | 2 | 0 |
| 32 | AC Milan | 2 | 0 | 0 | 2 | 0 |
| 33 | Red Star | 2 | 0 | 0 | 2 | 0 |
| 34 | Salzburg | 2 | 0 | 0 | 2 | 0 |
| 35 | Slovan Bratislava | 2 | 0 | 0 | 2 | 0 |
| 36 | Young Boys | 2 | 0 | 0 | 2 | 0 |
